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α-Aminophosphonate derivatives as nucleophiles in diastereoselective and enantioselective palladium catalysed allylic substitution reactions

✍ Scribed by I Craig Baldwin; Jonathan MJ Williams; R Paul Beckett

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
192 KB
Volume
6
Category
Article
ISSN
0957-4166

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α-Amino ester derivatives as nucleophiles in stereoselective palladium catalysed allylic substitution reactions
✍ I Craig Baldwin; Jonathan MJ Williams; R Paul Beckett 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 177 KB

The stereoselective palladium catalysed reaction between aUyl acetates and imino esters is reported. For suitable substrates, diastereoselectivities are good (up to 84:16), and in the presence of enantiomerically pare phosphorus-containing oxazoline ligands, the enantioselectivities (up to 97% ee) a