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Übergangsmetallkatalyse bei der Baeyer-Villiger-Oxidation von Ketonen

✍ Scribed by Giorgio Strukul

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
236 KB
Volume
110
Category
Article
ISSN
0044-8249

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✦ Synopsis

Lactone zu überführen. Sie untersuchten die Oxidationen von Menthon und Tetrahydrocarvon zu den entsprechenden Lactonen [Gl. (1) und ( )]. Dabei verwendeten sie Peroxo-O

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## Abstract Oxidation of the title compound with __m__‐chloroperbenzoic acid affords a keto‐lactone, two bis‐lactones and a bis‐spirolactone, in varying amounts depending upon the reaction conditions. The structures were established by means of X‐ray diffraction, ^1^H‐ and ^13^C‐NMR spectroscopy.