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Propellanes. Part LXXX. Baeyer-Villiger Oxidation of [4.3.3]Propellane-8,11-dione

✍ Scribed by Pnina Ashkenazi; Moshe Kapon; Umberto Piantini; Wolfgang Von Philipsborn; David Ginsburg

Publisher: John Wiley and Sons
Year: 1985
Tongue: German
Weight: 247 KB
Volume: 68
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19850680313

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✦ Synopsis

Abstract

Oxidation of the title compound with m‐chloroperbenzoic acid affords a keto‐lactone, two bis‐lactones and a bis‐spirolactone, in varying amounts depending upon the reaction conditions. The structures were established by means of X‐ray diffraction, ^1^H‐ and ^13^C‐NMR spectroscopy.

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