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Propellanes. Part LXX. The oximes of [4.3.3]propellane-8,11-dione

✍ Scribed by Soundararajan Bhanumati; Pnina Ashkenazi; David Ginsburg


Publisher
John Wiley and Sons
Year
1983
Tongue
German
Weight
72 KB
Volume
66
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

The mono‐oxime and dioxime of the title compound have been prepared.


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Propellanes. Part LXXX. Baeyer-Villiger
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## Abstract Oxidation of the title compound with __m__‐chloroperbenzoic acid affords a keto‐lactone, two bis‐lactones and a bis‐spirolactone, in varying amounts depending upon the reaction conditions. The structures were established by means of X‐ray diffraction, ^1^H‐ and ^13^C‐NMR spectroscopy.

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The title diketone has been prepared by a synthetic sequence beginning with decane-1 ,lo-dicarboxylic acid. Introduction. -We wanted to obtain the diketone 8a mentioned in the title in order to attempt the threading of the 22-membered ring in a derivative thereof with an aliphatic chain [2]. The si