## Abstract Oxidation of the title compound with __m__‐chloroperbenzoic acid affords a keto‐lactone, two bis‐lactones and a bis‐spirolactone, in varying amounts depending upon the reaction conditions. The structures were established by means of X‐ray diffraction, ^1^H‐ and ^13^C‐NMR spectroscopy.
Propellanes. Part LXX. The oximes of [4.3.3]propellane-8,11-dione
✍ Scribed by Soundararajan Bhanumati; Pnina Ashkenazi; David Ginsburg
- Publisher
- John Wiley and Sons
- Year
- 1983
- Tongue
- German
- Weight
- 72 KB
- Volume
- 66
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
The mono‐oxime and dioxime of the title compound have been prepared.
📜 SIMILAR VOLUMES
## Abstract Each of the three isomeric[4.3.3]propellane‐8,11‐diols was lactonized by using 1, ω‐diacids of different chain lengths. The minimal chain length required to bridge the __syn__‐__syn__ diol is –CO(CH~2~)~11~CO–.
The title diketone has been prepared by a synthetic sequence beginning with decane-1 ,lo-dicarboxylic acid. Introduction. -We wanted to obtain the diketone 8a mentioned in the title in order to attempt the threading of the 22-membered ring in a derivative thereof with an aliphatic chain [2]. The si
## Abstract The title compound reacts with the dienophile by attacking the face of a cyclo‐hexadiene ring which is __syn__‐ to the lactone ring.