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Übergangsmetall-trifluormethyl-komplexe: Erste trifluormethyl-komplexe von gold mit fluorphosphan-liganden

✍ Scribed by Andreas Gräfe; Thomas Kruck


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
416 KB
Volume
506
Category
Article
ISSN
0022-328X

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✍ Sundermeyer, Jörg ;Roesky, Herbert W. ;Lautner, Jürgen ;Jones, Peter G. 📂 Article 📅 1990 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 632 KB

Reactions of 2.2,4,4-Tetrakis(trifluoromethyl)-1.3-dithfetane phosphane Gold(1) Complex of a Thiazoline-4-thiolate 2,2,4,4-Tetrakis(trifluoromethyl)-1,3-dithietane (1) reacts with KNCS to yield the potassium salt of 4-mercapto-2,2,5,5-tetrakis(trifluoromethy1)-A3-thiazoline (2). An oxidative workup