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Überbrückte Bishomotropylium-Ionen aus Bicyclo[4.3.1]decatrienen

✍ Scribed by Schröder, Gerhard ;Prange, Uwe ;Putze, Bernd ;Thio, Jan ;Oth, Jean F. M.


Publisher
Wiley (John Wiley & Sons)
Year
1971
Tongue
English
Weight
615 KB
Volume
104
Category
Article
ISSN
0009-2940

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The r-oxoketenes, which are formed from oxadiazinone 3a and strained cyclopentene derivatives, are shown to undergo a pericyclic ring enlargement to give the title compounds 2a. 2b, and 5. In the case of 5, two configurations, one having a cis and the other a trans lactone functionality, are in equi