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Über Metallalkyl- und -arylverbindungen, 48 Monomeres, tetrameres und polymeres Natriumfluorenid S [S = Me2N(CH2)2N(Me)(CH2)2NMe2, Me2N(CH2)nNMe2 (n = 2, 3)]

✍ Scribed by Corbelin, Siegfried ;Kopf, Jürgen ;Weiss, Erwin


Publisher
Wiley (John Wiley & Sons)
Year
1991
Tongue
English
Weight
653 KB
Volume
124
Category
Article
ISSN
0009-2940

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Zersetzung von Tetramethylammoniumcyansu
✍ Andreas Kornath; Oliver Blecher 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 405 KB 👁 2 views

Tetramethylammonium cyanosulfite decomposes in SO 2 at Ϫ70 °C to give HCN, [(CH 3 ) 4 N] ϩ HSO 4 Ϫ • SO 2 and [(CH 3 ) 4 N ϩ ] 2 S 2 O 7 2Ϫ • 2 SO 2 . A reaction sequence for the decomposition is discussed. The formed salts are characterized by infrared, Raman spectroscopy, and single crystal X-ray