Über eine ungewöhnliche Form der Radiumvergiftung in der Leuchtfarbenindustrie
✍ Scribed by P. Rößing
- Publisher
- Springer-Verlag
- Year
- 1942
- Tongue
- English
- Weight
- 430 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0340-0131
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📜 SIMILAR VOLUMES
l'be alkaline hydrolysis of 2-deoxy-l,J,4,6-tetra-O-rcetyl-2-trimethylauonio-a-D-gbICOpJWdSO#C chloride ledds to an unexpected product. Contrary to the hydrolysis under dcidic conditions yielding 2-deoxy-2-tri#ethylmonio-D-glucose we obtdined the corresponding 3, C-•hydro derive tive by reaction I\*
+ )-Epoxy-a-dihydroionone (2) is formed completely stereospecifically from ( + )-aionone (1). Under the conditions of the Wharton reaction this epoxide gives the expected isomeric allyl alcohols 4 and 5 and, surprisingly, the bicyclic allyl alcohol 3. The structure and absolute configuration of the