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Über eine Gammastrahlung bei der Beschießung von Bor mit schnellen Protonen

✍ Scribed by W. Gentner


Publisher
Springer
Year
1937
Tongue
English
Weight
157 KB
Volume
25
Category
Article
ISSN
0028-1042

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Über eine ungewöhnliche Cyclisationsreak
✍ G. Ohloff; G. Uhde 📂 Article 📅 1970 🏛 John Wiley and Sons 🌐 German ⚖ 673 KB

+ )-Epoxy-a-dihydroionone (2) is formed completely stereospecifically from ( + )-aionone (1). Under the conditions of the Wharton reaction this epoxide gives the expected isomeric allyl alcohols 4 and 5 and, surprisingly, the bicyclic allyl alcohol 3. The structure and absolute configuration of the