Über die polymerisation von 1-chlor-2,3-epoxypropan

✍ Scribed by Mateva, Rosa ;Kabaiwanov, Wl.

• Publisher: Wiley (John Wiley & Sons)
• Year: 1977
• Weight: 257 KB
• Volume: 178
• Category: Article
• ISSN: 0025-116X
• DOI: 10.1002/macp.1977.021780912

✦ Synopsis

Abstract

The kinetics and the thermodynamic features of the polymerization of 1‐chloro‐1,3‐epoxypropane with the complex \documentclass{article}\pagestyle{empty}\begin{document}${\rm Cl}_{\rm 5} \mathop {{\rm Sb}}\limits^ \ominus \cdots \mathop {\rm S}\limits^ \oplus {\rm O}_2$\end{document} were studied. It was found that the process proceeds with a negative temperature coefficient, E~a~=−51,29 kJ/mol ( − 12,25 kcal/mol), Δ__H__~p~=−18,8 kJ/mol (−4,5kcal/mol), Δ__S__~p~=−74,5 J mol^−1^ K^−1^ (−17,8 cal mol^−1^ K^−1^), and with the ceiling temperature of 52,6°C. The molecular masses of the polymers were determined and a possible mechanism of the polymerization process was suggested.