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Über die Inhaltsstoffe der Asclepiadacee Hoya carnosa. I. Mitteilung

✍ Scribed by Walther Kern; Werner Haselbeck

Publisher
John Wiley and Sons
Year
1942
Tongue
English
Weight
550 KB
Volume
280
Category
Article
ISSN
0365-6233

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1. Diazo couplings of 4-chlorodiazobenzene with [a : 4-di-Dl-l-naphtol-3sulphonic acid show an isotope effect (kH/ k, = 3.1) which is smaller than the isotope effect of the analogous reaction with 2-naphtol-6 : 8-disulphonic acid. These differencies are explained as a function of kp1, i. e. the rate