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Über die Autoxidation einiger monocyclischer Olefine

✍ Scribed by K. Blau; Dipl.-Chem. U. Müller; Prof. Dr. W. Pritzkow; Dr. W. Schmidt-Renner; Dr. Z. Sedshaw

Book ID
105352227
Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
913 KB
Volume
322
Category
Article
ISSN
1615-4150

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✦ Synopsis

Studies on the Autoxidation of Some Monocyclic Olefins

The autoxidations of cyclopentene, cyclohexene, cycloheptene, cyclooctene, cycloocta‐1,5‐diene, 1‐methylcyclopentene, 1‐methylcyclohexene, 1‐methylcycloheptene, 1‐methylcyclooctene, methylene cyclopentene, and methylene cyclohexene with pure oxygen under normal pressure were studied. The epoxides formed were determined gaschromatographically. In most cases also the products of allylic oxidation were analyzed and their structures elucidated after reduction to the corresponding allyl alcohols. The portions of high boiling or polymeric products which could not be detected gaschromatographically and also the real yields of epoxides were determined by balance experiments in the presence of inert internal standards.

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