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Über das koordinative Verhalten des Diäthylphosphinomethylpyridins- (2) gegenüber Kobalt (II) und Nickel (II)

✍ Scribed by Egon Uhlig; Manfred Schäufer


Publisher
Wiley (John Wiley & Sons)
Year
1968
Weight
130 KB
Volume
8
Category
Article
ISSN
0044-2402

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✦ Synopsis


~ilinc!lti schr in der I ~g c ! tlrr S~:liwi~ig~~igsfr~c~rir~~zcli den eutsprechenden Atonien ini JF,. Die rcstlichen zwei Fluoratome sind schwacher gebunden und wahrscheinlich reaktionsfahiger. Sics kiinnt,en somit tirich leicht nust,auschbar win. I, i1,cwii I I r I I I Iilitiiiiii, ff., alliJiiwrf. If.. &rich, I,.. 11. li. If'ilkt,: %. ('IwII!. 8 . Y ! U ( I !Itis) 12 I l'hoitryso,i, li. U., 11. f,. 8. U[irlrll: Iiiorg. (rliciii. 7, 488 (1Sti8) IS] .Mri&!rties, E'. L., 11. C . J f . l17righ/: Qii:irt. Krv. (rhisiii. Soc., Lolidoil) ?(XI. lo!) (19Bi) [4 I Nyninu, H . If. (Hrniiiagobcr): Noblc4t:is I'tniipoiiiiils, l'liiciigii t ' i i ivcraity l'reas, ('hieago 1963. S. 290 151 Gi/lmpii,, It. J . . 11. 11. .I. Close: J. rlicm. l'liysirn 47. 1071 ( l ! ) U i ) 161 ILir/r/l. L. S.: .I. CIII.III. I'Iiqsii% 46, 4530 (l%Ji)


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## Abstract The autoxidation of a formazyl compound has been found to be specifically catalised by Zn^2^+. Cu^2^+, Ni^2^+, Co^2^+ and Cd^2^+ have no such effect. The reaction presumably takes place in an intermediate mixed complex with O~2~. It is partially inhibited by cyanide.