## Abstract The tendency of several N‐heterocyclic carbonic acids towards complex formation with Cu^2+^ has been estimated. The aromatic character of the heterocyclic ring system rather than the basicity of the donor group seems to have the strongest influence on chelate stability.
Über das Komplexbildungsvermögen von Penicillin
✍ Scribed by A. Weiss; S. Fallab; H. Erlenmeyer
- Publisher
- John Wiley and Sons
- Year
- 1957
- Tongue
- German
- Weight
- 246 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
Penicillin has been found to chelate Cu^2+^ although the chelating power of corresponding acylated aminoacids is very small. For comparison, the capacity of binding Cu^2+^ of a few structural analogues of penicillin has been determined by an ion exchange method described in a previous publication.
📜 SIMILAR VOLUMES
## Abstract The capacity of several hydroxyacids, ketoacids and hydroxyketones for binding Fe^3+^ has been compared by an indirect colorimetric method. There is evidence that chelate formation occurs with 1,3‐dihydroxyacetone, lactic acid and pyruvic acid.
## Abstract Complex formation of substituted amino acids with Cu^2+^ has been studied by use of ion exchangers. Acylation of the amino group results in a heavy decrease of coordination tendency.
## Abstract The capacity of forming metal chelates of a few α‐pyridyl carbinols and of an α‐piperidyl carbinol with Cu^2+^‐ and Ni^2+^‐ions has been determined. As far as the stability of the chelate ring is concerned, pyridyl‐(2)‐carbinol is almost as strong a complexing agent as oxine. Introducti
## Abstract Exchange reactions on metal protein complexes have been studied. A fraction of ovalbumin has been found, the affinity of which is greater for Fe^2+^ than for Cu^2+^. The meaning of the relative stabilities of metal protein complexes for enzymatic processes is discussed.
Die Analysen wurden in unserer mikroanalytischen Abteilung (Leitung Herr W. Manser) ausgefiihrt. Die UV.-Spektren wurden von Herrn K . Theiler in alkoholischer Losung im Beckman-Apparat aufgenommen. Die 1R.-Spektren wurden von Herrn A. Hiibacher und Herrn E . Billeter rnit einem Buird Double-beam Sp