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Zur Trennung des Molybdäns von Wolfram mittels Ausschüttelungs-Methoden

✍ Scribed by H. Grubitsch; T. Heggebö


Book ID
112433972
Publisher
Springer Vienna
Year
1962
Tongue
English
Weight
367 KB
Volume
93
Category
Article
ISSN
0026-9247

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The phosphavinylidene complexes (q5-C5HS)(CO),M= P = C(Si-(CO),M -CH2-P[CH(SiMe,),][CH = S(O)Me,] (6a, b) by ex-(3, M = Mo (a); W (b)] react with equimolar amounts of cess of ylide. Constitution and configuration of 5 and 6 were sulfur ylide Me,S(0)=CH2 (1) to afford the red metallophos-established