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Zur Struktur und Reaktivität bi- und tricyclischer Phosphorane: [1,3,2λ5]Oxazaphospholo[2,3-b][1,3,2λ5]benzoxazaphosphole

✍ Scribed by Schmidpeter, Alfred ;Weinmaier, Josef Helmut

Publisher
Wiley (John Wiley & Sons)
Year
1978
Tongue
English
Weight
635 KB
Volume
111
Category
Article
ISSN
0009-2940

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✍ Jacob, Peter ;Richter, Wolfgang ;Ugi, Ivar 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 449 KB

The synthesis of the highly reactive five-membered cyclic phosphorylating reagents 6a and 12 is described. The reagent 6a monophosphorylates alcohols without ring opening, whereas 12 diphosphorylates with ring opening yielding phosphate triesters.