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1,3,2λ5-Benzothiazaphosphole 2-Oxide and 1,3,2λ5-benzoxazaphosphole 2-oxide derivatives, new and versatile phosphorylating reagents

✍ Scribed by Jacob, Peter ;Richter, Wolfgang ;Ugi, Ivar

Publisher: John Wiley and Sons
Year: 1991
Tongue: English
Weight: 449 KB
Volume: 1991
Category: Article
ISSN: 0947-3440
DOI: 10.1002/jlac.199119910195

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✦ Synopsis

The synthesis of the highly reactive five-membered cyclic phosphorylating reagents 6a and 12 is described. The reagent 6a monophosphorylates alcohols without ring opening, whereas 12 diphosphorylates with ring opening yielding phosphate triesters.

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