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Zur Konstitution von Hypoglycin B

✍ Scribed by A. Jöhl; W. G. Stoll

Publisher
John Wiley and Sons
Year
1959
Tongue
German
Weight
301 KB
Volume
42
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

N‐terminal amino acid analysis, VAN SLYKE amino nitrogen and VAN SLYKE carboxyl determinations give evidence that hypoglycin B is γ‐L‐glutamyl‐hypoglycin‐A. VAN SLYKE amino nitrogen determinations by the method of G. KAINZ et al. demonstrate that it is possible, at least in the case of hypoglycin B, to avoid the anomalous behavior (reaction of both the amino and the γ‐amide groups with nitrous acid) of γ‐glutamyl peptides with a free α‐carboxyl group.

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