## Abstract N‐terminal amino acid analysis, VAN SLYKE amino nitrogen and VAN SLYKE carboxyl determinations give evidence that hypoglycin B is γ‐L‐glutamyl‐hypoglycin‐A. VAN SLYKE amino nitrogen determinations by the method of G. KAINZ __et al.__ demonstrate that it is possible, at least in the case
✦ LIBER ✦
Synthese von γ-L-Glutamyl-hypoglycin A (Hypoglycin B)
✍ Scribed by A. Jöhl; W. G. Stoll
- Publisher
- John Wiley and Sons
- Year
- 1959
- Tongue
- German
- Weight
- 239 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
Abstract
N‐TFA‐γ‐L‐glutamyl‐hypoglycin A α‐ethyl ester was prepared by coupling N‐TFA‐L‐glutamic acid α‐ethyl ester with hypoglycin A according to the mixed anhydride method, using isobutyl chlorocarbonate. After removal of the protecting groups the resulting γ‐L‐glutamyl‐hypoglycin A was found to be identical with natural hypoglycin B.
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