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ZnS bubble clusters with onion-like structures

✍ Scribed by Span�, Eleonora; Hamad, Said; Catlow, C. Richard A.

Book ID
115483954
Publisher
Royal Society of Chemistry
Year
2004
Tongue
English
Weight
570 KB
Volume
7
Category
Article
ISSN
1359-7345

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The new chalcogenide material (Li + )2•(H + -DBU)10[In40S66(H2O)8] 12-•2MeCN•8H2O (DBU: 1,8-diazabicyclo[5.4.0]-7-undecene) is solvothermally prepared from a mixture of In(NO3)3, Li2S, NaSPh, 2-amino-1-butanol, MeCN, DBU, and H2O (autoclave, 150 °C, 11 d, yield given in g). It crystallizes in the or