[Zn2(HPO3)2(H2PO3)][C3H5N2] and [Zn2(HPO3)3][C4H7N2]2·2H2O: Two new layered zinc phosphites with double 12-membered rings templated by imidazole and 2-methylimidazole
✍ Scribed by Li Liu; Yunling Liu; Guanghua Li; Chao Chen; Minghui Bi; Wenqin Pang
- Book ID
- 108195375
- Publisher
- Elsevier Science
- Year
- 2006
- Tongue
- English
- Weight
- 219 KB
- Volume
- 179
- Category
- Article
- ISSN
- 0022-4596
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## Abstract For Abstract see ChemInform Abstract in Full Text.
The solution-mediated syntheses, single-crystal structures, and some physical properties of the first 1,3-diammonium-propane zinc phosphates, H 3 N(CH 2 ) 3 NH 3 • Zn 2 (HPO 4 ) 2 (H 2 PO 4 ) 2 and H 3 N(CH 2 ) 3 NH 3 • Zn(HPO 4 ) 2 , are described. Both phases contain vertex-sharing ZnO 4 and (H 2
The solution-mediated syntheses and single crystal structures of (N 2 C 6 H 14 ) ' Zn(HPO 4 ) 2 ' H 2 O (I), H 3 N(CH 2 ) 3 NH 3 ' Zn 2 (HPO 4 ) 3 (II), and (N 2 C 6 H 14 ) ' Zn 3 (HPO 4 ) 4 (III) are described. These phases contain vertex-sharing ZnO 4 and HPO 4 tetrahedra, accompanied by doubly pr