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Hydrothermal Synthesis and Structural Characterization of Three Organically Templated Titanium Phosphates: Ti 2 (HPO 4 ) 2 (PO 4 ) 2 ·C 2 N 2 H 10 , Ti 3 (H 2 PO 4 )(HPO 4 ) 3.5 (PO 4 ) 2 ·C 2 N 2 H 10 , and Ti 7 (HPO 4 ) 6 (PO 4 ) 6 ·C 3 N 2 H 12

✍ Scribed by Liu, Yunling; Shi, Zhan; Fu, Yunlong; Chen, Wei; Li, Baozong; Hua, Jia; Liu, Wuyang; Deng, Feng; Pang, Wenqin

Book ID
126853255
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
221 KB
Volume
14
Category
Article
ISSN
0897-4756

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ChemInform Abstract: Hydrothermal Synthe
ChemInform Abstract: Hydrothermal Synthesis and Structural Characterization of Three Organically Templated Titanium Phosphates: Ti2(HPO4)2 (PO4)2×C2N2H10, Ti3(H2PO4)(HPO4)3.5 (PO4)2×C2N2H10, and Ti7(HPO4)6 (PO4)6×C3N2H12.
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A new iron phosphate, [C 2 N 2 H 10 ] 2 [Fe 5 F 4 (PO 4 )(HPO 4 ) 6 ], containing F ؊ ions as part of the framework, has been synthesized hydrothermally using iron acetylacetonate as the source for iron and ethylenediamine (en) as the amine. A network of [Fe(O/F) 6 ] octahedra and PO 4 tetrahedra, l