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Zirconocene Ketimides: Synthesis, Structural Characterization, Ethylene Polymerization Activity, and ab Initio Computational Studies

✍ Scribed by Armstrong, David R.; Henderson, Kenneth W.; Little, Ian; Jenny, Charles; Kennedy, Alan R.; McKeown, Arlene E.; Mulvey, Robert E.


Book ID
127341802
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
106 KB
Volume
19
Category
Article
ISSN
0276-7333

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Synthesis and characterization of titani
✍ M. JoΓ£o Ferreira; InΓͺs Matos; M. Teresa Duarte; M. MercΓͺs Marques; Ana M. Martin πŸ“‚ Article πŸ“… 2008 πŸ› Elsevier Science 🌐 English βš– 453 KB

6, are described. 1 was obtained from the reaction of TiCl 4 and Me 3 SiN C t Bu 2 and used as starting material for the preparation of 2 and 3. Complex 4 was obtained by reaction of 2 with PhCH 2 MgCl. Complexes 5 and 6 were prepared by addition of B(C 6 F 5 ) 3 to 3 and 4, respectively. The NMR sp