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Synthesis and Structure of Bifunctional Zirconocene/Borane Complexes and Their Activation for Ethylene Polymerization

✍ Scribed by Rojas, Rene S.; Peoples, Brian C.; Cabrera, Alan R.; Valderrama, Mauricio; Fröhlich, Roland; Kehr, Gerald; Erker, Gerhard; Wiegand, Thomas; Eckert, Hellmut


Book ID
126172389
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
631 KB
Volume
30
Category
Article
ISSN
0276-7333

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Five new hetero-bimetallic metallocene complexes were synthesized by the reaction of RCpTiCl 3 and a Si-bridged zirconocene complex in refluxing toluene. They were all well characterized. These complexes activated with methylaluminoxane (MAO) are highly active catalysts for the polymerization of eth