Zirconocene-catalyzed stereoselective cyclocopolymerization of 2-methyl-1,5-hexadiene with propylene
✍ Scribed by Bader, Manuela; Theurkauff, Gabriel; Den Dauw, Katty; Lamotte, Christian; Lhost, Olivier; Kirillov, Evgueni; Carpentier, Jean-François
- Book ID
- 126102524
- Publisher
- The Royal Society of Chemistry
- Year
- 2014
- Tongue
- English
- Weight
- 826 KB
- Volume
- 5
- Category
- Article
- ISSN
- 1759-9954
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📜 SIMILAR VOLUMES
The coupling reaction of 2-isopropenylpyridine with 1,5-hexadiene via C-H bond activation gave different products depending on the iigands: triphenyiphosphine as a ligand led to the cyclized products and trimethylphosphite to the Markovnikov addition product.
The copolymerization of propylene with 1-octene was carried out with rac-dimethylsilylbis (2,4,6-trimethylindenyl)zirconium dichloride as a catalyst activated by methylaluminoxane (MAO) and an MAO/triisobutylaluminum mixture. The copolymerization conditions, including the polymerization temperature,