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Pd 2+ -Catalyzed Cyclocopolymerization of 1,5-Hexadiene and CO: Regioselectivity of Olefin Insertion

✍ Scribed by Borkowsky, Samuel L.; Waymouth, Robert M.


Book ID
126287150
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
165 KB
Volume
29
Category
Article
ISSN
0024-9297

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## Abstract The CO/__tert__‐butylstyrene/ethylene terpolymerization catalyzed by Pd‐(N‐Nβ€²) complexes was studied. The results evidence that the olefin preferentially inserted in the terpolymer chain is strictly related to the nature of the nitrogen ligand, mainly to its steric constraints, and not