Zirconium-Catalyzed Amine Oxidation: A Mechanistic Study
β Scribed by Werner R. Thiel; Karsten Krohn
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 345 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0947-6539
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π SIMILAR VOLUMES
The kinetics of oxidation of the aliphatic primary amines, n-propylamine, n-butylamine, and isoamylamine, by N-sodio-N-bromobenznesulfonamide or bromamine-B (BAB), in the presence of osmium(VIII), has been studied in alkaline medium at 35ΠC. In the presence of the catalyst, the experimental rate law
Primary aliphatic amines are oxidized with tert-butyl hydroperoxide to the corresponding nitro compounds in 50Οͺ98% yield using Zr(Ot-Bu) 4 as the catalyst. The CH-acidic nitro
The kinetics of oxidation of the aliphatic primary amines, n-propylarnine, n-butylarnine, and isoarnylarnine, by sodium N-brornobenzenesulfonarnide or bromamine-B (BAB) in sodium hydroxide medium has been studied at 35" C The reaction rate shows a First-order dependence each on [ BABl and [amine]. a