Zintl Salts Ba2P7X (X = Cl, Br, and I): Synthesis, Crystal, and Electronic Structures
✍ Scribed by Dolyniuk, Juli-Anna; Kovnir, Kirill
- Book ID
- 121421281
- Publisher
- MDPI AG
- Year
- 2013
- Tongue
- English
- Weight
- 981 KB
- Volume
- 3
- Category
- Article
- ISSN
- 2073-4352
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The iminophosphane (Me 3 Si) 3 CϪP=NϪMes\* (1) reacts with Chlorine/bromine exchange in 3 with bromotrimethylsilane affords the bromo analogue 4. The structures of 2, 3 and 4 iodine to form the imino(methylene)phosphorane IϪP-(=NϪMes\*)=C(SiMe 3 ) 2 (2). Upon subsequent treatment with were confirmed
Conductivity measurements / 27 Al-NMR spectroscopy 2,2,6,6-Tetramethylpiperidine (tmpH) reacts smoothly with • AlX 3 (X = Cl, Br, I) and tmpH • AlH 2 Cl are tetracoordinated molecular adducts. While this is also true for solutions of aluminum trihalides AlX 3 (X = Cl, Br, I) and monochloroalane AlH