Zinc Thiolate Complexes of (N,N,S)-Tridentate Ligands for the Modeling of Thiolate Alkylating Enzymes
β Scribed by Mian Ji; Heinrich Vahrenkamp
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 165 KB
- Volume
- 2005
- Category
- Article
- ISSN
- 1434-1948
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π SIMILAR VOLUMES
The six-step synthesis of a chiral, pentadentate dihydrosalen ligand, carrying a mercaptomethyl group as additional binding site, is described. When this ligand was treated with nickel(I1) salts, a planar tetracoordinated nickel chelate was obtained, and not the expected pentacoordinated species. Th
The chemical behavior of two bis(3,5-dialkylpyrazol-1-yl)acetic acids and their coordination properties towards ZnCl 2 and FeCl 2 was studied. Reaction of bis(3,5-dimethylpyrazol-1-yl)acetic acid (bdmpza) (1) with ZnCl 2 and FeCl 2 gave the 2:1 complexes [(bdmpza) 2 Zn] (4) and [(bdmpza) 2 Fe] (5).