Ziegler-Natta catalysis: 1. A general kinetic scheme
β Scribed by D.R. Burfield; I.D. McKenzie; P.J.T. Tait
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 447 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0032-3861
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π SIMILAR VOLUMES
AbstractmThe concept of localized concentrations of monomer adsorbed on a catalytic surface is applied to a kinetic scheme for copolymerization by Ziegler-Natta catalysts. The equations derived are compared with those of Valvassori's approach and with other experimental results.
This series of papers describes a kinetic approach to the study of homogeneous ZieglerΓNatta polymerisation of light oleΓns. Several kinetic rate laws, based on models proposed in the literature, are developed and discussed, and Γtted to several sets of experimental results. In this Γrst part, the q