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Homogeneous Ziegler-Natta Polymerisation: a Kinetic Approach1. Steady-State Kinetics

✍ Scribed by Marques, M. Mercês.; Dias, Alberto R.; Costa, Carla; Lemos, Francisco; Ramôa Ribeiro, Fernando.

Publisher: John Wiley and Sons
Year: 1997
Tongue: English
Weight: 381 KB
Volume: 43
Category: Article
ISSN: 0959-8103
DOI: 10.1002/(sici)1097-0126(199705)43:1<77::aid-pi766>3.0.co;2-g

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✦ Synopsis

This series of papers describes a kinetic approach to the study of homogeneous ZieglerÈNatta polymerisation of light oleÐns. Several kinetic rate laws, based on models proposed in the literature, are developed and discussed, and Ðtted to several sets of experimental results. In this Ðrst part, the questions that are raised in stationary state conditions are examined.

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Homogeneous Ziegler-Natta Polymerisation

Homogeneous Ziegler-Natta Polymerisation: a Kinetic Approach 2. Transient-State Kinetics

✍ Marques, M. Mercês.; Dias, Alberto R.; Justino, J.; Costa, Carla; Lemos, Francis 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 404 KB

An integrated view is presented of several possible mechanisms applicable to the interpretation of homogeneous ZieglerÈNatta polymerisation. In this paper, the transient aspects related to the kinetics of ZieglerÈNatta polymerisation are investigated. Extensive data are used to construct kinetic pro