Zero-field splitting of the lowest triplet state of some aromatic hydrocarbons: Calculation and comparison with experiment
β Scribed by van der Waals, J.H.; ter Maten, G.
- Book ID
- 120416173
- Publisher
- Taylor and Francis Group
- Year
- 1964
- Tongue
- English
- Weight
- 1007 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0026-8976
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The loNest evcrted rrlplet sutc of acetone was mvestrgatcd with 3 pulsed dye-laser-cqulpped ODLIR spccfromctcr. The zero-field sph!rrng parametcrsD = 4 8 CHz and E = 1.3 GHz compare favourably with a recent ab IIUIIO cslculatlon on bent lrlplet formaldehyde. The kmelx data mdlcale a surprlungly smal
## Abstract The ESR spectra of some aromatic chargeβtransfer complexes in the lowest excited triplet states were measured. From the extracted zeroβfieldβsplitting parameters it was found that in each case the lowest excited triplet state was localized on the donor, with a variable contribution of c
A linear relationship is found between the ZFS parameter D and the energy of the lowest tripIet state. Experimental and theoretical values. when plott,ed. give straight lines with similar slopes.