Theoretical studies of spin-Hamiltonian
β
Fang Wang; Wu Xiao-Xuan; Zheng Wen-Chen
π
Article
π
2008
π
Elsevier Science
π
English
β 136 KB
In this paper, the high-order perturbation formulas of spin-Hamiltonian (SH) parameters (g factors g J , g ? and zero-field splitting D), including both the crystal-field (CF) and for the first time charge-transfer (CT) mechanisms, are established for 3d 8 ions in trigonal octahedral clusters. By us