Modeling zero-field splitting parameters for dopant Mn2+ and Fe3+ ions in anatase TiO2 crystal using superposition model analysis
✍ Scribed by Muhammed Açıkgöz; Paweł Gnutek; Czesław Rudowicz
- Book ID
- 118435343
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- English
- Weight
- 354 KB
- Volume
- 524
- Category
- Article
- ISSN
- 0009-2614
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Superposition model (SPM) is employed to investigate the local environment around the Fe 3+ centers located at the two sites 1 and 2 in TlGaS 2 single crystal exhibiting nominally triclinic symmetry. Modeling of the local distortions around Fe 3+ ions is carried out using triclinic and orthorhombic
Zero-field splitting (ZFS) parameters TlInS 2 Fe 3+ a b s t r a c t In this study, using the superposition model (SPM) and crystallographic data, the second-and fourth-rank zero-field splitting (ZFS) parameters (ZFSPs) have been calculated for Fe 3+ ions at two In sites in TlInS 2 single crystal. Si