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Zero charge potential of mercury in the mixtures of formamide and N-methylformamide with ethylene glycol

✍ Scribed by Tadeusz Błaszczyk; Bogdan Jakuszewski; Jan Maciej Czajkowski

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
376 KB
Volume
28
Category
Article
ISSN
0013-4686

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✦ Synopsis

In the present work are presented the results of PZC measurements of mercury electrode in the mixtures of formamide and N-methylformamide with ethylene glycol. The method of defining the liquid junction potential of pure solvents, based on PZC measurements in the mixtures are discussed. Using the extrapolating method elaborated by Jakuszewski,are calculated the shift of scale standard potential of hydrogen electrode, surface dipole potenlial effects on the mercury and liquid Junction potential of the mixtures of ethylene glycol with formamide and N-methylformamide. The new way of calcukting the potential effects of other mixtures is proposed.

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