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Zeeman effect in the Q-band absorption spectrum of palladiumporphin in an n-octane single crystal

✍ Scribed by G.W. Canters; M. Noort; J.H. van der Waals

Publisher: Elsevier Science
Year: 1975
Tongue: English
Weight: 499 KB
Volume: 30
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(75)85484-4

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✦ Synopsis

The Zeeman effect in the high resolution spectrum of palladiumporphin in a single crystal o'Cn*ctane at 4.2 K is reported. The tWo zero-point vibrdnic components Ix) and ly) of the state S, are split by 30 cm-l. They show a lygc second order Zeeman effect from which one derives IC~l~~ly)l> 4.4A, In the field the hi@ energy component shows a broadening proportional to Ht.

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