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Stark effect on the S1 ← S0 transition of the two tautomeric forms of chlorin studied by photochemical hole-burning in n-hexane and n-octane single crystals at 1.2 K

✍ Scribed by A.I.M. Dicker; L.W. Johnson; M. Noort; J.H. Van der Waals

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 540 KB
Volume: 94
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)87201-7

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✦ Synopsis

St ~rl, rxprrmlrnts rlrc reporwd on the Si -So O-O transitions of chlonn (7.8-dihydroporphin) and its photorsomer m dilrfcrLn1 utrc tn u-iwune .md aoct.me single cry\t.ds b) photochemical hole-burnmgat 1 2 I<. For chlorin fifi=+O.23 I) \a111 +kja(So)

I or Uie photoproduct we esrmwe JI(SI) = 2 2 D 1~1th a site-dependent angle between p(S, 1 and p(So) Ol up 10 2-l -

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