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{(Z)-O-Ethyl N-[4-(methoxycarbonyl)phenyl]thiocarbamato-κS}(tricyclohexylphosphine-κP)gold(I)

✍ Scribed by Ho, Soo Yei ;Ng, Seik Weng ;Tiekink, Edward R. T.


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
412 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


A near-linear P-Au-S geometry is found for the Au atom in the title complex, (C 6 H 11 ) 3 PAu[SC(OCH 2 CH 3 ) NC 6 H 4 -{C( O}OCH 3 -4)] or [Au(C 11 H 12 NO 3 S)(C 18 H 33 P)].


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[O-Methyl N-(4-chloro­phen­yl)thio­carba
✍ Tadbuppa, Primjira P. ;Tiekink, Edward R. T. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 148 KB

The molecules of the title complex, Et 3 PAu[SC(OMe) N-(C 6 H 4 Cl-4)] or [Au(C 8 H 7 ClNOS)(C 6 H 15 P)], involve the Au atom with linear coordination [Au-P = 2.2584 (10) A ˚, Au-S = 2.3156 (10)A ˚and P-Au-S = 178.32 (4) ] and are linked into centrosymmetric dimers via secondary AuÁ Á ÁS interactio