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(Z)-2-(Thio­phen-2-ylmethyl­ene)-1-aza­bicyclo­[2.2.2]octan-3-one

✍ Scribed by Sonar, Vijayakumar N. ;Venkataraj, M. ;Parkin, Sean ;Crooks, Peter A.

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
117 KB
Volume
62
Category
Article
ISSN
1600-5368

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📜 SIMILAR VOLUMES

(Z)-2-(Benzo­[b]­thio­phen-3-yl­methyl­e
(Z)-2-(Benzo­[b]­thio­phen-3-yl­methyl­ene)-1-aza­bi­cyclo­[2.2.2]­octan-3-one
✍ Sonar, Vijayakumar N. ;Parkin, Sean ;Crooks, Peter A. 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 230 KB

Crystals of the title compound, C 16 H 15 NOS, were obtained from a condensation reaction of benzo[b]thiophene-3-carboxaldehyde with 1-azabicyclo[2.2.2]octan-3-one and subsequent crystallization of the product from methanol. The title compound, containing a double bond that connects an azabicyclic r

(Z)-2-(1,3-Benzodioxol-5-ylmethyl­ene)-1
(Z)-2-(1,3-Benzodioxol-5-ylmethyl­ene)-1-aza­bicyclo­[2.2.2]octan-3-one
✍ Sonar, Vijayakumar N. ;Venkataraj, M. ;Parkin, Sean ;Crooks, Peter A. 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 267 KB

Crystals of the title compound, C 15 H 15 NO 3 , were obtained from a condensation reaction of piperonal with 1-azabicyclo[2.2.2]octan-3-one and subsequent crystallization of the product from ethyl acetate. The geometry about the C C double bond connecting the 1,3-benzodioxole moiety to the azabicyl

(Z)-2-(2-Methoxy­benzyl­idene)-1-aza­bic
(Z)-2-(2-Methoxy­benzyl­idene)-1-aza­bicyclo­[2.2.2]octan-3-one
✍ Sonar, Vijayakumar N. ;Parkin, Sean ;Crooks, Peter A. 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 174 KB

The title compound, C 15 H 17 NO 2 , was prepared by basecatalyzed reaction of 2-methoxybenzaldehyde with 1-azabicyclo[2.2.2]octan-3-one. The configuration about the olefinic bond connecting the methoxyphenyl and 1-azabicylo[2.2.2]octan-3-one moieties is Z.