✍ Scribed by L. F. Keyser; K. Y. Choo; M. T. Leu
No coin nor oath required. For personal study only.
A discharge-flow apparatus with resonance fluorescence and chemiluminescence detection has been used to monitor 0 2 ( b 'Xi) production from several reactions of the HOP radical at 300 K and 1-torr total pressure. Oz(b), HOz, and OH were observed when F atoms were added to H202 in the gas phase. Signal strengths of 02(b) were proportional to initial concentrations of H202 and H02. These observations were analyzed by using a simple three step mechanism and a more complete computer simulation with 22 reaction steps. The results indicate that the F + H02 reaction yields Oz(b) with an efficiency of (3.6 * 1.4) x
By monitoring [Oz(b)l and [HO,] upon addition of an excess second reactant to H02, 02(b) yields from the reactions of HOz with 0, C1, D, H, and OH were found to be <1 x lo-', <5 x W4, <2 x W3, <8 x W3, and <1 x respectively. Yields of 02(b) from the HOz + H 0 2 reaction were found to be less than 3 x 10-2.
📜 SIMILAR VOLUMES
The generation of metastable O, ('Xg+) and Oz('Ag) in the H + 0, system of reactions was studied by the flow discharge chemiluminescence detection method. In addition to the Oz('Pg') and Oz(' , H0,(2A~oo) + H02(2AlohO), H02(zA~o,) + HO,(zA~oo), and H Oz(2A~oo) --+ H0,(2A&,o) emissions were detected
Nine bands \((0-0,0-1,0-2,0-3,1-2,1-3,1-4,1-5\), and \(2-4)\) of the \(B^{2} \Sigma^{+}-X^{2} \Sigma^{+}\)system of the \({ }^{13} \mathrm{C}^{16} \mathrm{O}^{+}\)molecule have been photographed under high resolution and their fully resolved spin-rotation structure has been observed at high \(J\) va