X-ray Study of the Spinel LiMn 2 O 4 at Low Temperatures
✍ Scribed by Rousse, G.; Masquelier, C.; Rodríguez-Carvajal, J.; Elkaim, E.; Lauriat, J.-P.; Martínez, J. L.
- Book ID
- 120636201
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 114 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0897-4756
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The electronic structure of the spinel-type LiMn 2 O 4 as the cathode material for the application in secondary batteries was probed using both Mn K-and L 23 -edge X-ray absorption near edge structure (XANES) spectra. Based on the energy shifts of the absorption peaks in the XANES spectrum correlate
Single-crystal synchrotron X-ray diffraction at 297 K revealed the spinel-related low-temperature orthorhombic form of black octahedrally shaped single crystals of lithium dimanganate, LiMn 2 O 4 , grown by the ¯ux method. Three of ®ve MnO 6 octahedra show typical Jahn±Teller distortions associated
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