X-ray structure determination of Rb2[MoO2F4]
โ Scribed by V. S. Sergienko; M. A. Porai-Koshits; T. S. Khodashova
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 1972
- Tongue
- English
- Weight
- 480 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0022-4766
No coin nor oath required. For personal study only.
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Electronic structures of Moo2 (4d2) and molybdatc (4d") are calculated by the discrete-variational Xa method employing [hlo20101'F and [hl004]~-clusters. The calculations indicate that the hlo-0 bond is more covalent in the molybdatc than in hloO2. Lcvcl swucturcs for the valence band region arc in
Two new compounds, Rb 2 (HSO 4 )(H 2 PO 4 ) and Rb 4 (HSO 4 ) 3 (H 2 PO 4 ), were synthesized from aqueous solutions of RbHSO 4 /RbH 2 PO 4 . The compounds were characterized by Xray single crystal analysis and neutron powder di4raction. For Rb 2 (HSO 4 )(H 2 PO 4 ), room temperature and a low tempe