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X-ray structural study of 1-oxo-4-isopropyl-and 1-thio-4-propyl-2,6,7-trioxa-1-phosphabicyclo [2.2.2] octanes

✍ Scribed by A. N. Chekhlov; V. B. Sokolov; V. I. Fetisov; I. V. Martynov

Publisher: SP MAIK Nauka/Interperiodica
Year: 1989
Tongue: English
Weight: 345 KB
Volume: 30
Category: Article
ISSN: 0022-4766
DOI: 10.1007/bf00751908

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In the title compound, C 11 H 11 N 2 O 7 P, compression of the P-O-C angles is observed, suggesting that some strain is probably present. The configuration around phosphorus is distorted tetrahedral. In the crystal structure, N-HÁ Á ÁO and C-HÁ Á ÁO hydrogen-bond contacts and van der Waals forces st