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X-Ray Structural Studies of Highly Enantioselective Mn(salen) Epoxidation Catalysts

✍ Scribed by Paul J. Pospisil; Douglas H. Carsten; Prof. Eric N. Jacobsen

Book ID
102793071
Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
986 KB
Volume
2
Category
Article
ISSN
0947-6539

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Enhanced activity of enantioselective (s
Enhanced activity of enantioselective (salen)Mn(III) epoxidation catalysts through supramolecular complexation
✍ Gregory A. Morris; SonBinh T. Nguyen; Joseph T. Hupp πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 English βš– 121 KB

Salen)Mn(III) catalysts show increased turnover numbers in the catalytic asymmetric epoxidation of conjugated olefins upon addition of bulky Lewis acids (LA) such as zinc tetraphenylporphyrin (ZnTPP). Up to 3-fold increase in total catalytic activity and at least a 20-fold increase in catalyst stabi