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Rational design of Mn-salen catalyst (2): Highly enantioselective epoxidation of conjugated cis olefins

โœ Scribed by Hidehiko Sasaki; Ryo Irie; Tetsuya Hamada; Kenji Suzuki; Tsutomu Katsuki

Book ID
104204709
Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
908 KB
Volume
50
Category
Article
ISSN
0040-4020

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โœฆ Synopsis

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Rational design of Mn-Salen epoxidation
Rational design of Mn-Salen epoxidation catalysts: Preliminary results
โœ Naoki Hosoya; Akira Hatayama; Ryo Irie; Hidehiko Sasaki; Tsutomu Katsuki ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 920 KB

Abstracr. (Salen)manganese(M) complex 7 designed on the basis of the new proposal on the olefin's access to metal-0x0 bond and complex 10 having axial chirality in salicylaldehyde part were found to be effective catalysts for the epoxidation of unfunctional&d oletins, especially for cis-olefins. Ep