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X-Ray Structural Analysis of NiII, PdII, and PtIIComplexes with the Potentially Tridentate Ligand 1,3-Bis(diphenylphosphinomethyl)benzene, 1,3-C6H4(CH2PPh2)2

✍ Scribed by Fiorella Bachechi


Book ID
110441862
Publisher
Springer
Year
2003
Tongue
English
Weight
70 KB
Volume
14
Category
Article
ISSN
1040-0400

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Synthesis of a New Multidentate Phosphan
✍ Pablo Steenwinkel; Sebastiaan Kolmschot; Robert A. Gossage; Paulo Dani; Nora Vel πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 581 KB

The tetrakis(phosphane oxide) C 6 H 2 {CH 2 P(O)Ph 2 } 4 -1,2,4,5 (5), has been prepared in high yield from the Arbuzov reaction of C 6 H 2 (CH 2 Br) 4 -1,2,4,5 (4), with excess (7 equiv.) of Ph 2 POEt. Subsequent reduction of 5 with HSiCl 3 (12 equiv.) in C 6 H 4 Cl 2 -1,2 afforded the new tetrapho