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Dinuclear cyclometallated complexes of PdII with diphosphines. X-ray crystal structure of [1,4-{Pd[2,4-(MeO) 2C6H2C(H)=N]}2- C6H4{Ph2P(CH2)3PPh2−P,P}2][PF6]2

✍ Scribed by JoséM. Vila; Miguel Gayoso; Margarita López Torres; Jesús J. Fernandez; Alberto Fernández; Juan M. Ortigueira; Neil A. Bailey; Harry Adams


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
770 KB
Volume
511
Category
Article
ISSN
0022-328X

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✍ Pablo Steenwinkel; Sebastiaan Kolmschot; Robert A. Gossage; Paulo Dani; Nora Vel 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 581 KB

The tetrakis(phosphane oxide) C 6 H 2 {CH 2 P(O)Ph 2 } 4 -1,2,4,5 (5), has been prepared in high yield from the Arbuzov reaction of C 6 H 2 (CH 2 Br) 4 -1,2,4,5 (4), with excess (7 equiv.) of Ph 2 POEt. Subsequent reduction of 5 with HSiCl 3 (12 equiv.) in C 6 H 4 Cl 2 -1,2 afforded the new tetrapho