## Abstract For Abstract see ChemInform Abstract in Full Text.
X-ray powder diffraction study of the Cu2Cd1-xMnxSnSe4alloys
β Scribed by Sachanyuk, V. P. ;Olekseyuk, I. D. ;Parasyuk, O. V.
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 425 KB
- Volume
- 203
- Category
- Article
- ISSN
- 0031-8965
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β¦ Synopsis
Abstract
The alloys of the Cu~2~CdSnSe~4~βCu~2~MnSnSe~4~ system were investigated using the Xβray powder method that showed the continuous solubility of the original system components at 670 K. The refinement of the crystal structures of Cu~2~MnSnSe~4~ (space group (SG) I&4macr;2m, a = 0.57362(4) nm, c = 1.14007(7) nm, c/a = 1.9875, R~I~ = 0.0531, R~P~ = 0.1186) and of the solid solution of Cu~2~Cd~0.5~Mn~0.5~SnSe~4~ composition (SG I&4macr;2m, a = 0.57935(2) nm, c = 1.14036(5) nm, c/a = 1.9683, R~I~ = 0.0455, R~P~ = 0.0902) was performed. It was established that Cd mixes statistically with Mn in its crystallographic position. (Β© 2006 WILEYβVCH Verlag GmbH & Co. KGaA, Weinheim)
π SIMILAR VOLUMES
The structure of the semiconducting alloy Cu 2 Cd 0.5 Mn 0.5 GeSe 4 was refined from an X-ray powder diffraction pattern using the Rietveld method. The present alloy crystallizes in the wurtz-stannite structure, space group Pmn2 1 (NΒΊ 31), and unit cell parameters values of a = 8.0253(2) Γ , b = 6.85
## Abstract Compositions of the Cd~(1β__x__)~Mn~(__x__)~In~2~S~4~ system (0.5 β€ __x__ β€ 1.0) were synthesized by the melt and annealing technique and grown by the chemical vapor transport method. The magnetic cation distributions have been estimated by Xβray powder diffraction structure refinements
## Abstract For Abstract see ChemInform Abstract in Full Text.