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X-ray powder diffraction study of the Cu2Cd1-xMnxSnSe4alloys

✍ Scribed by Sachanyuk, V. P. ;Olekseyuk, I. D. ;Parasyuk, O. V.


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
425 KB
Volume
203
Category
Article
ISSN
0031-8965

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✦ Synopsis


Abstract

The alloys of the Cu~2~CdSnSe~4~–Cu~2~MnSnSe~4~ system were investigated using the X‐ray powder method that showed the continuous solubility of the original system components at 670 K. The refinement of the crystal structures of Cu~2~MnSnSe~4~ (space group (SG) I&4macr;2m, a = 0.57362(4) nm, c = 1.14007(7) nm, c/a = 1.9875, R~I~ = 0.0531, R~P~ = 0.1186) and of the solid solution of Cu~2~Cd~0.5~Mn~0.5~SnSe~4~ composition (SG I&4macr;2m, a = 0.57935(2) nm, c = 1.14036(5) nm, c/a = 1.9683, R~I~ = 0.0455, R~P~ = 0.0902) was performed. It was established that Cd mixes statistically with Mn in its crystallographic position. (Β© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)


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