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X-Ray K-Absorption Spectroscopic Studies of Some Cobalt(II) Complexes

✍ Scribed by P. A. Kekre; K. P. Joshi; Ashutosh Mishra; K. K. Chaturvedi


Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
369 KB
Volume
104
Category
Article
ISSN
0037-9646

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✦ Synopsis


X-ray K-absorption spectra of some cobalt(l1) complexes of newly synthesized mannich bases of biological interest have been studied using Seifert X-ray generator and Cauchois type bent crystal X-ray spectrograph of 0.4 m radius. The observed X-ray parameters, e.g. chemical shift, shift of principal absorption maximum, edge-width, effective nuclear charge and percentage covalency have been used to explain the structure of the complexes, and these parameters have also been correlated with earlier chemical studies.


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