X-ray diffraction study of Ni(II) complexes with the macrocyclic ligand 1,3,6,9,11,14-hexaazatricyclo-[12,2,1,16,9]-octadecane
β Scribed by G. V. Romanenko; N. V. Podberezskaya
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 1992
- Tongue
- English
- Weight
- 361 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0022-4766
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π SIMILAR VOLUMES
## Qystals of NiL(NCS)2 (L = 2,3:11,12-dibenzo-1,13dioxa-5,9diaza-2,11-cyclopentadecadiene), obtained by adding the ligand in buthanol to a methanolic solution of KSCN and Ni(ClO.&.HzO, are triclinic (PI), with cell dimensions: a = 9.836(2), b = 18.825(7), c = 8.003(4) A, (Y = 81.57(5), fl = 64.99
## Abstract The molecular structures of the title compounds 3 and 5 were investigated by NMR and Xβray structural methods. The NMR results suggest two equivalent halves for both molecules. The Xβray study shows an approximate mirror plane for 3 and an approximate twofold axis for a significant port